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Study of physical properties of the Li0.5MgFe1.5O3.5 ferrite nanoparticles

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In the present research study, the structural, optical, magnetic, electrical and dielectrical properties of the spinel ferrite Li0.5MgFe1.5O3.5, synthesized using a sol–gel auto-combustion method were studied. X-ray diffraction, Fourier transform… Click to show full abstract

In the present research study, the structural, optical, magnetic, electrical and dielectrical properties of the spinel ferrite Li0.5MgFe1.5O3.5, synthesized using a sol–gel auto-combustion method were studied. X-ray diffraction, Fourier transform infrared spectroscopy (FTIR), and Raman spectroscopy revealed that this sample crystallizes in a cubic spinel structure with space group Fd3̄m. Moreover, the optical investigation by UV-visible spectroscopy has revealed that the band gap for our sample is (Eg = 2.87 eV), which shows that our compound is a potential candidate for optoelectronic applications. The values of the remanent magnetization Mr = 0.13 emu g−1, of the coercive field HC = 4.65 Oe deduced from the hysteresis loop, are very low, suggesting the superparamagnetic behavior of our sample. Additionally, the temperature coefficient of resistance (TCR) is −19% affirmed that Li0.5MgFe1.5O3.5 ferrite is a good candidate for detecting infrared radiation and infrared bolometric applications. Indeed, the activation energies were calculated from the imaginary part of the impedance, the electrical conductivity, and the imaginary part of the modulus, thus demonstrating that the charge carriers involved in the processes of conduction and relaxation are the same.

Keywords: li0 5mgfe1; 5o3 ferrite; spectroscopy; physical properties; 5mgfe1 5o3; study physical

Journal Title: RSC Advances
Year Published: 2023

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