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Arsolyl-supported intermetallic dative bonding

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The first examples of late transition metal η5-arsolyls (L = CO, P(OMe)3; R = Ph, Me, Et, SiMe3; R′ = Ph, H, Me, Et, Me) serve as ditopic donors to… Click to show full abstract

The first examples of late transition metal η5-arsolyls (L = CO, P(OMe)3; R = Ph, Me, Et, SiMe3; R′ = Ph, H, Me, Et, Me) serve as ditopic donors to extraneous metal centres (M = PtII, AuI, HgII) through both conventional As → M and polar-covalent (dative) Co → M interactions.

Keywords: dative bonding; arsolyl supported; supported intermetallic; intermetallic dative

Journal Title: Chemical Science
Year Published: 2022

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