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Suppression of self-stratification in colloidal mixtures with high Péclet numbers.

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The non-equilibrium assembly of bimodal colloids during evaporative processes is an attractive means to achieve gradient or stratified layers in thick films. Here, we show that the stratification of small… Click to show full abstract

The non-equilibrium assembly of bimodal colloids during evaporative processes is an attractive means to achieve gradient or stratified layers in thick films. Here, we show that the stratification of small colloids on top of large is prevented when the viscosity of the continuous aqueous phase is too high. We propose a model where a too narrow width of the gradient in concentration of small colloids suppresses the stratification.

Keywords: suppression self; colloidal mixtures; stratification; mixtures high; stratification colloidal; self stratification

Journal Title: Soft matter
Year Published: 2022

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