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DMSO/tBuONa/O2-mediated efficient syntheses of diverse quinoxalines through α-imino radicals.

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Herein, we describe an efficient method involving the synthesis of diverse quinoxalines using the DMSO/tBuONa/O2 system as a single-electron oxidant to form α-imino radicals and nitrogen radicals for the direct… Click to show full abstract

Herein, we describe an efficient method involving the synthesis of diverse quinoxalines using the DMSO/tBuONa/O2 system as a single-electron oxidant to form α-imino radicals and nitrogen radicals for the direct construction of C-N bonds. This methodology provides a novel approach to form α-imino radicals with good reactivity.

Keywords: imino radicals; dmso tbuona; mediated efficient; tbuona mediated; imino; diverse quinoxalines

Journal Title: Chemical communications
Year Published: 2023

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