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The reactive HO˙/(Salophent-Bu)Co(II) radical pair was observed to be generated via homolysis of the terminal Co(III)-OH bond in transient (Salophent-Bu)(L)Co(III)(OH) (L = Py, MeOH) complexes as indicated by UV-Vis and… Click to show full abstract
The reactive HO˙/(Salophent-Bu)Co(II) radical pair was observed to be generated via homolysis of the terminal Co(III)-OH bond in transient (Salophent-Bu)(L)Co(III)(OH) (L = Py, MeOH) complexes as indicated by UV-Vis and EPR measurements. Based on this elementary process, C-H bond activations in acetone, 2-butanone, acetonitrile and benzene were achieved under ambient conditions. For the reactions of the first three substrates, the alkylcobalt(III) complexes were formed as the products.
Keywords:
radical pair;
iii;
generated via;
salophent radical;
via homolysis;
bond
Journal Title: Chemical communications
Year Published: 2023
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2023
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!