Commercially available Co2(CO)8 was used as an effective catalyst for the hydrosilylation of nitroarenes under both thermal and photochemical conditions. A wide variety of nitroarenes with various functionalities were selectively… Click to show full abstract
Commercially available Co2(CO)8 was used as an effective catalyst for the hydrosilylation of nitroarenes under both thermal and photochemical conditions. A wide variety of nitroarenes with various functionalities were selectively reduced to aromatic amines. Syntheses of drug molecules expand the potential utility of this protocol. Experimental evidence suggested a radical pathway.
Keywords:
cobalt catalyzed;
catalyzed chemoselective;
hydrosilylation;
chemoselective reduction;
reduction nitroarenes;
thermal photochemical
Journal Title: Chemical communications
Year Published: 2023
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Journal Title: Chemical communications
Year Published: 2023
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!