We report the use of nitrone C-H groups as hydrogen bond donors for binding anions. Acyclic anion receptors with two nitrone moieties were synthesized by condensation reactions between aryl-aldehydes and… Click to show full abstract
We report the use of nitrone C-H groups as hydrogen bond donors for binding anions. Acyclic anion receptors with two nitrone moieties were synthesized by condensation reactions between aryl-aldehydes and m-phenylenedihydroxylamines. The solid-state structure of dinitrones revealed C-H⋯O hydrogen bonds. Anion binding properties were investigated using NMR titration with halide and phosphate salts.
Keywords:
receptors nitrone;
anion receptors;
bond donors;
hydrogen bond
Journal Title: Chemical communications
Year Published: 2023
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Journal Title: Chemical communications
Year Published: 2023
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!