A solution-phase synthesis of colloidally stable A2BF6 nanocrystals is reported for the first time, focusing on A+ = Cs+, NH4+ and B4+ = Zr4+. Handling hypertoxic HF is avoided by… Click to show full abstract
A solution-phase synthesis of colloidally stable A2BF6 nanocrystals is reported for the first time, focusing on A+ = Cs+, NH4+ and B4+ = Zr4+. Handling hypertoxic HF is avoided by using NH4F and a low-boiling-point alcohol, representing the first synthesis of any A2BF6 nanocrystals without HF addition. The chemical incompatability of Zr4+ with other common fluoride sources is discussed.
Keywords:
cs2zrf6 nh4;
nh4 2zrf6;
synthesis colloidal;
synthesis;
colloidal cs2zrf6;
free synthesis
Journal Title: Chemical communications
Year Published: 2023
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Journal Title: Chemical communications
Year Published: 2023
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!