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Phenoxazine-based small molecule heterojunction nanoparticles for photocatalytic hydrogen production.

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A phenoxazine-based small organic molecular donor POZ-M is designed and synthesized to prepare organic heterojunction nanoparticles (NPs) with a small molecular acceptor ITIC for photocatalytic hydrogen production, giving a reaction… Click to show full abstract

A phenoxazine-based small organic molecular donor POZ-M is designed and synthesized to prepare organic heterojunction nanoparticles (NPs) with a small molecular acceptor ITIC for photocatalytic hydrogen production, giving a reaction rate of up to 63 mmol g-1 h-1. A beneficial molecular design strategy highlights the role of miscibility between POZ-M and ITIC, which is necessary to achieve satisfactory charge separation at the donor/acceptor interface.

Keywords: hydrogen production; based small; heterojunction nanoparticles; phenoxazine based; photocatalytic hydrogen

Journal Title: Chemical communications
Year Published: 2023

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