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A photochromic metallacycle with highly anisotropic Dy-F magnetic units.

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A dinuclear metallacycle assembled from a bispyridyl dithienylethene linker and a highly anisotropic dysprosium based Single Molecule Magnet (SMM) shows magnetic hysteresis at 1.8 K together with photoisomerization in single… Click to show full abstract

A dinuclear metallacycle assembled from a bispyridyl dithienylethene linker and a highly anisotropic dysprosium based Single Molecule Magnet (SMM) shows magnetic hysteresis at 1.8 K together with photoisomerization in single crystals (SC). The impact of photoswitching on the SMM behavior is evidenced and related to the specific organization of the magnetic units.

Keywords: photochromic metallacycle; magnetic units; anisotropic magnetic; metallacycle highly; highly anisotropic

Journal Title: Chemical communications
Year Published: 2023

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