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Modulating the metal center in MIL-101 for the piezoelectric catalytic synthesis of hydrogen peroxide.

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Modulation of metal centers is a promising strategy to boost catalytic performance. Two structurally identical MOFs with different metal centers, namely MIL-101(Cr) and MIL-101(Fe), were synthesized. MIL-101(Cr) exhibits superior H2O2… Click to show full abstract

Modulation of metal centers is a promising strategy to boost catalytic performance. Two structurally identical MOFs with different metal centers, namely MIL-101(Cr) and MIL-101(Fe), were synthesized. MIL-101(Cr) exhibits superior H2O2 yield due to Cr's electron-donating ability. This work helps in developing the rational design and optimization of MOF catalysts for catalytic reactions.

Keywords: metal center; modulating metal; mil 101; metal; center mil

Journal Title: Chemical communications
Year Published: 2023

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