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Remote template effect in the synthesis of bipyridine-strapped porphyrins.

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A bipyridine-strapped porphyrin was prepared using a remote template effect of alkali or transition metal cations in the bipyridine subunit to enhance the yield 10-fold. The flexibility of the bipyridine-strap… Click to show full abstract

A bipyridine-strapped porphyrin was prepared using a remote template effect of alkali or transition metal cations in the bipyridine subunit to enhance the yield 10-fold. The flexibility of the bipyridine-strap also allowed the synthesis of a doubly strapped porphyrin.

Keywords: remote template; bipyridine; synthesis; template effect; bipyridine strapped

Journal Title: Chemical communications
Year Published: 2023

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