Orifices with ring-atom counts of up to 13 have been created on [70]fullerenes as an isolable form. Herein, we report orifice-enlargement reactions providing huge orifices on [70]fullerene with ring-atom counts… Click to show full abstract
Orifices with ring-atom counts of up to 13 have been created on [70]fullerenes as an isolable form. Herein, we report orifice-enlargement reactions providing huge orifices on [70]fullerene with ring-atom counts of 17, 18, and 20. These orifices allow H2O, N2, and Ar to be encapulated in situ inside the open-[70]fullerene cavity.
               
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