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A robust multigram-scale synthesis of 1,3-disubstituted cubanes (previously only available on milligram-scale) is reported. The approach exploits a readily available enone intermediate previously used for the synthesis of 1,4-disubstituted cubanes,… Click to show full abstract
A robust multigram-scale synthesis of 1,3-disubstituted cubanes (previously only available on milligram-scale) is reported. The approach exploits a readily available enone intermediate previously used for the synthesis of 1,4-disubstituted cubanes, by introducing a novel Wharton transposition to access useful quantities of 1,3-disubstituted cubanes for diverse applications.
Keywords:
synthesis disubstituted;
disubstituted cubane;
disubstituted cubanes;
cubane derivatives;
synthesis;
practical synthesis
Journal Title: Chemical Communications
Year Published: 2023
Link to full text (if available)
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Journal Title: Chemical Communications
Year Published: 2023
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!