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Stable cyclopalladated complexes containing an (sp3)C-Pd bond were synthesized via α-CH2 deprotonation and palladation of N-alkyl groups of carbene ligands bearing electron-withdrawing substituents. The strong electron donating strengths of the… Click to show full abstract
Stable cyclopalladated complexes containing an (sp3)C-Pd bond were synthesized via α-CH2 deprotonation and palladation of N-alkyl groups of carbene ligands bearing electron-withdrawing substituents. The strong electron donating strengths of the resulting CNHC^Csp3 chelators were experimentally identified, and the palladacycle underwent template-directed, versatile C-halogenation with X2.
Keywords:
cnhc csp3;
palladacycle;
halogenation via;
versatile halogenation
Journal Title: Dalton transactions
Year Published: 2023
Link to full text (if available)
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Journal Title: Dalton transactions
Year Published: 2023
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!