Photo by jareddrice from unsplash
Inclusion structures incorporating more than one guest molecule are elusive because confinement alters their molecular properties. We report the solid-state characterization of an inclusion complex comprising two γ-cyclodextrins and two… Click to show full abstract
Inclusion structures incorporating more than one guest molecule are elusive because confinement alters their molecular properties. We report the solid-state characterization of an inclusion complex comprising two γ-cyclodextrins and two [Cu(2-pyridinemethanolate)(2-pyridinemethanol)]PF6 units. Quantum calculation reveals that interfragment charge transfer occurs. The confined Cu fragment and the unincluded "linear chain [Cu(2-pyridinemethanolate)(2-pyridinemethanol)]PF6" exhibit different properties.
Journal Title: Dalton transactions
Year Published: 2023
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!