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Reaction of a transiently formed terminal phosphinidene complex with triethylamine resulted in the formation of an sp3 C-H insertion product, as revealed by 31P NMR spectroscopy, which was isolated as… Click to show full abstract
Reaction of a transiently formed terminal phosphinidene complex with triethylamine resulted in the formation of an sp3 C-H insertion product, as revealed by 31P NMR spectroscopy, which was isolated as semi-solid compound. However, if the reaction was continued for 24 h, a primary phosphane complex was obtained eventually. The compounds were characterised by NMR spectroscopy and mass spectrometry. Formation of the final products is explained by a mechanistic proposal based on DFT calculations.
Keywords:
terminal phosphinidene;
reaction;
triethylamine;
spectroscopy;
phosphinidene complex
Journal Title: Dalton transactions
Year Published: 2023
Link to full text (if available)
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Journal Title: Dalton transactions
Year Published: 2023
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!