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The reactivities of two selected phosphanylphosphaalkenes, Ph2CP-PtBu2 (1a) and (p-MeO-Ph)2CP-PtBu2 (1b), toward CuCl, AgCl and (tht)AuCl (tht = tetrahydrothiophene) were investigated. As a result, new phosphanylphosphaalkene dimeric and monomeric complexes… Click to show full abstract
The reactivities of two selected phosphanylphosphaalkenes, Ph2CP-PtBu2 (1a) and (p-MeO-Ph)2CP-PtBu2 (1b), toward CuCl, AgCl and (tht)AuCl (tht = tetrahydrothiophene) were investigated. As a result, new phosphanylphosphaalkene dimeric and monomeric complexes were formed (Cu and Ag dimeric and Au monomeric). All obtained products were air and moisture stable and light insensitive.
Keywords:
group complexes;
ligand preparation;
preparation stability;
phosphanylphosphaalkene ligand;
stability study;
complexes phosphanylphosphaalkene
Journal Title: Dalton transactions
Year Published: 2023
Link to full text (if available)
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Journal Title: Dalton transactions
Year Published: 2023
Link to full text (if available)
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recommendations!