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Herein we report the B(3,4,5-F3H2C6)3-catalysed C3-allylation of indoles using allylic esters. 25 examples of C3-allylated products are presented in up to 97% yield. The mechanism for the reaction was explored… Click to show full abstract
Herein we report the B(3,4,5-F3H2C6)3-catalysed C3-allylation of indoles using allylic esters. 25 examples of C3-allylated products are presented in up to 97% yield. The mechanism for the reaction was explored using detailed Density Functional Theory (DFT) studies.
Keywords:
catalysed allylation;
acid catalysed;
lewis acid;
f3h2c6 lewis;
allylation indoles
Journal Title: Dalton transactions
Year Published: 2023
Link to full text (if available)
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Journal Title: Dalton transactions
Year Published: 2023
Link to full text (if available)
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recommendations!