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Low-chlorinated fullerenes, dimeric (C60Cl5)2 and one-dimensional, polymeric (C60Cl4)∞, were obtained by high-temperature (270 °C) chlorination of C60 with a SbCl5/SbCl3 mixture, as revealed by X-ray crystallography. The compounds were characterized… Click to show full abstract
Low-chlorinated fullerenes, dimeric (C60Cl5)2 and one-dimensional, polymeric (C60Cl4)∞, were obtained by high-temperature (270 °C) chlorination of C60 with a SbCl5/SbCl3 mixture, as revealed by X-ray crystallography. The compounds were characterized by IR and Raman spectroscopy and theoretical calculations. This is the first observation of a fullerene polymer with single C-C bonding and neutral building blocks.
Keywords:
dimeric polymeric;
polymeric low;
c60;
c60 fullerenes;
low chlorinated;
chlorinated c60
Journal Title: Dalton transactions
Year Published: 2023
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Journal Title: Dalton transactions
Year Published: 2023
Link to full text (if available)
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recommendations!