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C2-Symmetric Atropisomeric N-Heterocyclic Carbene-Palladium(II) Complexes: Synthesis, Chiral Resolution and Application in enantioselective α-Arylation of Amides

The concept of atropisomeric N-heterocyclic carbene (NHC)-metal complexes was extended to NHCs possessing a C2-symmetry and implemented to prepare of palladium-based complexes. An in-depth study of the NHC precursors and... Click to show full abstract

The concept of atropisomeric N-heterocyclic carbene (NHC)-metal complexes was extended to NHCs possessing a C2-symmetry and implemented to prepare of palladium-based complexes. An in-depth study of the NHC precursors and...

Keywords: carbene palladium; atropisomeric heterocyclic; symmetric atropisomeric; heterocyclic carbene

Journal Title: Dalton Transactions
Year Published: 2023

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