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Germanium- and Tin-Bridged Diazulenylmethyl Cations: Effects of the Group 14 Element on the Structure and Properties of the π-Extended Cation

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Diazulenylmethyl cations bridged with a germanium and tin moiety were synthesized. In these cations, the nature of these elements has impacts on the chemical stability and photophysical properties. Upon aggregation,… Click to show full abstract

Diazulenylmethyl cations bridged with a germanium and tin moiety were synthesized. In these cations, the nature of these elements has impacts on the chemical stability and photophysical properties. Upon aggregation, these cations exhibit absorption bands in the near-infrared region, which are slightly blue-shifted compared to those of silicon-bridged congeners.

Keywords: germanium tin; cations effects; bridged diazulenylmethyl; tin bridged; diazulenylmethyl cations

Journal Title: Dalton Transactions
Year Published: 2023

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