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Highly photo- and triboluminescent lanthanide(III) coordination polymers based on diphosphine dioxides containing azaheterocyclic linkers

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The reaction of Eu(III) and Tb(III) hexafluoroacetylacetonates (hfac‒) with 2,4-bis(diphenylphosphino)pyrimidine dioxide (L1), 4,6-bis(diphenylphosphino)pyrimidine dioxide (L2), or 3,6-bis(diphenylphosphino)pyridazine dioxide (L3) afforded a new series of one-dimensional coordination polymers [LnL(hfac)3]n (L =... Click to show full abstract

The reaction of Eu(III) and Tb(III) hexafluoroacetylacetonates (hfac‒) with 2,4-bis(diphenylphosphino)pyrimidine dioxide (L1), 4,6-bis(diphenylphosphino)pyrimidine dioxide (L2), or 3,6-bis(diphenylphosphino)pyridazine dioxide (L3) afforded a new series of one-dimensional coordination polymers [LnL(hfac)3]n (L =...

Keywords: highly photo; bis diphenylphosphino; iii; coordination polymers; photo triboluminescent

Journal Title: New Journal of Chemistry
Year Published: 2023

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