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Ligand-directed structure evolution from titanium-oxo cluster to coordination capsule and one-dimensional coordination polymer based on {Ti3O} unit

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By modulating the geometry and size of ligand and using phosphite as bridging linker, {Ti3(μ3-O)} can be assembled into discrete {Ti6} cluster, coordination capsule {Ti18Cu3} and one-dimensional coordination polymer {Ti6}n. Click to show full abstract

By modulating the geometry and size of ligand and using phosphite as bridging linker, {Ti3(μ3-O)} can be assembled into discrete {Ti6} cluster, coordination capsule {Ti18Cu3} and one-dimensional coordination polymer {Ti6}n.

Keywords: coordination polymer; coordination; coordination capsule; dimensional coordination; one dimensional; cluster coordination

Journal Title: New Journal of Chemistry
Year Published: 2023

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