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Hexacoordinated Co(II) complex exhibiting strong magnetic anisotropy and field-induced slow magnetization relaxation: synthesis, magnetic characterization, and quantum-chemical modelling

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Hexacoordinated Co(II) complex of [CoL(NCS)2]·2DMSO (1) composition, where L is tetradentate bis-quinolyl hydrazone 2,2'-(2,2'-(butane-2,3-diylidene)bis(hydrazin-1-yl-2-ylidene))diquinoline, has been synthesised and characterized by IR, SCXRD, and AC and DC magnetic measurements. Due to... Click to show full abstract

Hexacoordinated Co(II) complex of [CoL(NCS)2]·2DMSO (1) composition, where L is tetradentate bis-quinolyl hydrazone 2,2'-(2,2'-(butane-2,3-diylidene)bis(hydrazin-1-yl-2-ylidene))diquinoline, has been synthesised and characterized by IR, SCXRD, and AC and DC magnetic measurements. Due to...

Keywords: strong magnetic; hexacoordinated complex; magnetic anisotropy; exhibiting strong; anisotropy field; complex exhibiting

Journal Title: New Journal of Chemistry
Year Published: 2023

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