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Alkylborane initiated RAFT polymerization: impact of carboxylic acid deblockers

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Oxygen-tolerant, alkylborane initiated RAFT has a partial order rate dependence of 1 for the acid concentration, supporting a homolytic substitution mechanism, and can be conducted with diminished deblocker concentrations when… Click to show full abstract

Oxygen-tolerant, alkylborane initiated RAFT has a partial order rate dependence of 1 for the acid concentration, supporting a homolytic substitution mechanism, and can be conducted with diminished deblocker concentrations when using stronger acids.

Keywords: polymerization impact; carboxylic acid; initiated raft; alkylborane initiated; raft polymerization; impact carboxylic

Journal Title: Polymer Chemistry
Year Published: 2023

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