Oxygen-tolerant, alkylborane initiated RAFT has a partial order rate dependence of 1 for the acid concentration, supporting a homolytic substitution mechanism, and can be conducted with diminished deblocker concentrations when… Click to show full abstract
Oxygen-tolerant, alkylborane initiated RAFT has a partial order rate dependence of 1 for the acid concentration, supporting a homolytic substitution mechanism, and can be conducted with diminished deblocker concentrations when using stronger acids.
               
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