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Accelerated Rates of Proton Coupled Electron Transfer to Oxygen Deficient Polyoxovanadate-alkoxide Clusters

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Anionic dopants, such as O-atom vacancies, alter the thermochemical and kinetic parameters of proton-coupled electron transfer (PCET) at metal oxide surfaces; understanding the impact is essential for informed material design... Click to show full abstract

Anionic dopants, such as O-atom vacancies, alter the thermochemical and kinetic parameters of proton-coupled electron transfer (PCET) at metal oxide surfaces; understanding the impact is essential for informed material design...

Keywords: electron transfer; accelerated rates; proton coupled; coupled electron

Journal Title: Inorganic Chemistry Frontiers
Year Published: 2023

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