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Mechanistic insights into the electrochemical reduction of CO2 to CO on Ni(salphen) complexes

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Cyclic voltammetry and bulk electrolysis showed that [Ni(II)(salphen)] [1], [Ni(II)(tBu-salphen)] [2], and a binuclear Ni(II) compound combining salphen and tBu-salphen [3] react with CO2 to yield a metal-carbonyl species that... Click to show full abstract

Cyclic voltammetry and bulk electrolysis showed that [Ni(II)(salphen)] [1], [Ni(II)(tBu-salphen)] [2], and a binuclear Ni(II) compound combining salphen and tBu-salphen [3] react with CO2 to yield a metal-carbonyl species that...

Keywords: mechanistic insights; reduction co2; co2 salphen; salphen; electrochemical reduction; insights electrochemical

Journal Title: Inorganic Chemistry Frontiers
Year Published: 2023

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