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Fluoride Counterion Boosts Gold(I) Catalysis: Case Studies for Hydrodefluorination and CO2 Hydrosilylation

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We reported herein a novel gold(I) bifluoride complex, LAuHF2, supported by a sterically bulky ligand (L, tBuXantphos), displays exceptional reactivity toward hydrodefluorination (HDF) and hydrosilylation of CO2 in the presence... Click to show full abstract

We reported herein a novel gold(I) bifluoride complex, LAuHF2, supported by a sterically bulky ligand (L, tBuXantphos), displays exceptional reactivity toward hydrodefluorination (HDF) and hydrosilylation of CO2 in the presence...

Keywords: gold catalysis; fluoride counterion; boosts gold; catalysis case; counterion boosts; hydrosilylation

Journal Title: Inorganic Chemistry Frontiers
Year Published: 2023

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