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Mechanistic Understanding on the Dual Gold and Photoredox-Catalyzed Thiosulfonylation of Alkynes and Enynes: A DFT Study

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The detailed mechanisms of the dual gold and photoredox-catalyzed thiosulfonylation of alkynes and 1,6-enynes with PhSO2SCF3 (1) were explored by DFT calculations. Computational results show that the complex of Au(I)…1... Click to show full abstract

The detailed mechanisms of the dual gold and photoredox-catalyzed thiosulfonylation of alkynes and 1,6-enynes with PhSO2SCF3 (1) were explored by DFT calculations. Computational results show that the complex of Au(I)…1...

Keywords: thiosulfonylation alkynes; alkynes enynes; catalyzed thiosulfonylation; dual gold; photoredox catalyzed; gold photoredox

Journal Title: Organic Chemistry Frontiers
Year Published: 2023

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