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Substrate-dependent Mechanism for Nickel-catalyzed N-allylation with Allylic Alcohols: Nucleophilic Attack vs Reductive Elimination

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Transition metal catalyzed amination of allylic alcohols via π-allylmetal is generally accepted to undergo a nucleophilic attack mechanism. However, we herein found the possibility of the competition between the reductive... Click to show full abstract

Transition metal catalyzed amination of allylic alcohols via π-allylmetal is generally accepted to undergo a nucleophilic attack mechanism. However, we herein found the possibility of the competition between the reductive...

Keywords: allylic alcohols; substrate dependent; nucleophilic attack; mechanism

Journal Title: Organic Chemistry Frontiers
Year Published: 2023

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