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The Synthesis, Properties, and Application of o-Carborane-based π-Conjugated Macrocycles

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Two o-carborane-based π-conjugated macrocycles are synthesized via oxidative coupling of acetylene-terminated o-carborane precursors. The single-crystal X-ray diffraction analysis unambiguously revealed their unique porous supramolecular structures, which display micropore characteristics. The... Click to show full abstract

Two o-carborane-based π-conjugated macrocycles are synthesized via oxidative coupling of acetylene-terminated o-carborane precursors. The single-crystal X-ray diffraction analysis unambiguously revealed their unique porous supramolecular structures, which display micropore characteristics. The...

Keywords: conjugated macrocycles; carborane based; properties application; carborane; synthesis properties; based conjugated

Journal Title: Organic Chemistry Frontiers
Year Published: 2023

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