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Aza-Wolff Rearrangement of N-Fluoroalkyl Triazoles to Ketenimines

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N-Fluoroalkylated 1,2,3-triazoles underwent a microwave-heating-assisted ring opening, nitrogen molecule elimination and concomitant group rearrangement to form isolable N-fluoroalkylketenimines. This reagent-free process is characterized by a wide scope and high efficiency... Click to show full abstract

N-Fluoroalkylated 1,2,3-triazoles underwent a microwave-heating-assisted ring opening, nitrogen molecule elimination and concomitant group rearrangement to form isolable N-fluoroalkylketenimines. This reagent-free process is characterized by a wide scope and high efficiency...

Keywords: rearrangement fluoroalkyl; fluoroalkyl triazoles; chemistry; triazoles ketenimines; aza wolff; wolff rearrangement

Journal Title: Organic Chemistry Frontiers
Year Published: 2023

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