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Phosphanyl-substituted tin half-sandwich complexes

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Phosphanyl-substituted tin(ii) half sandwich complexes are reported. Due to the Lewis acidic tin center and Lewis basic phosphorous atom they form head-to-tail dimers. Their properties and reactivities were investigated both… Click to show full abstract

Phosphanyl-substituted tin(ii) half sandwich complexes are reported. Due to the Lewis acidic tin center and Lewis basic phosphorous atom they form head-to-tail dimers. Their properties and reactivities were investigated both experimentally and theoretically. Furthermore, related transition metal complexes of these species are presented.

Keywords: sandwich complexes; half sandwich; substituted tin; phosphanyl substituted; tin half

Journal Title: RSC Advances
Year Published: 2023

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