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The new fluorocarbynes [M( Created by potrace 1.16, written by Peter Selinger 2001-2019 CF)(CO)2(Tp*)] (M = Mo, W; Tp* = tris(dimethylpyrazolyl)borate) arise from electrophilic fluorination of the lithiocarbynes [M(CLi)(CO)2(Tp*)] with… Click to show full abstract
The new fluorocarbynes [M( CF)(CO)2(Tp*)] (M = Mo, W; Tp* = tris(dimethylpyrazolyl)borate) arise from electrophilic fluorination of the lithiocarbynes [M(CLi)(CO)2(Tp*)] with FN(SO2Ph)2. The reactions of [W(CF)(CO)2(Tp*)] with [AuCl(SMe2)] and PhICl2 afford the first μ2-fluorocarbyne complex [WAu(μ-CF)Cl(CO)2(Tp*)] and the first high oxidation state fluorocarbyne [W(CF)Cl2(Tp*)], respectively.
Keywords:
600 600;
600 40z;
fluorocarbyne complexes;
electrophilic fluorination;
complexes via
Journal Title: Chemical Science
Year Published: 2023
Link to full text (if available)
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Journal Title: Chemical Science
Year Published: 2023
Link to full text (if available)
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recommendations!