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Selective Multifunctionalization of N-Heterocyclic Carbene Boranes via the Intermediacy of Boron-Centered Radical

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Selective difunctionalization of N-heterocyclic carbene (NHC) boranes with alkenes has been achieved via the decatungstate and thiol synergistic catalysis. The catalytic system also allows the stepwise trifunctionalization, leading to complex... Click to show full abstract

Selective difunctionalization of N-heterocyclic carbene (NHC) boranes with alkenes has been achieved via the decatungstate and thiol synergistic catalysis. The catalytic system also allows the stepwise trifunctionalization, leading to complex...

Keywords: carbene boranes; selective multifunctionalization; heterocyclic carbene; boranes via; carbene; multifunctionalization heterocyclic

Journal Title: Chemical Science
Year Published: 2023

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