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Ultrafast transient absorption spectra were recorded for solutions of [MnIII(cyclam)(H2O)(OTf)][OTf]2 (cyclam = 1,4,8,11-tetraazacyclotetradecane and OTf = Trifluoromethanesulfonate) in water to explore the possibility to restrict the equatorial expansion following photoexcitation... Click to show full abstract
Ultrafast transient absorption spectra were recorded for solutions of [MnIII(cyclam)(H2O)(OTf)][OTf]2 (cyclam = 1,4,8,11-tetraazacyclotetradecane and OTf = Trifluoromethanesulfonate) in water to explore the possibility to restrict the equatorial expansion following photoexcitation...
Keywords:
cyclam;
photoinduced jahn;
equatorial restriction;
restriction photoinduced;
jahn teller;
teller switch
Journal Title: Chemical Science
Year Published: 2023
Link to full text (if available)
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Journal Title: Chemical Science
Year Published: 2023
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!