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Photoactivable malachite green-based alkynylplatinum(II) 2,6-bis(N-alkylbenzimidazol-2-yl)pyridine complexes.

Photo-responsive malachite green moieties have been incorporated into an alkynylplatinum(II) bzimpy system. The photo-caged complexes in acetonitrile solutions exhibit self-assembly properties modulable by photo-removal of the cyano protecting group. Distinct… Click to show full abstract

Photo-responsive malachite green moieties have been incorporated into an alkynylplatinum(II) bzimpy system. The photo-caged complexes in acetonitrile solutions exhibit self-assembly properties modulable by photo-removal of the cyano protecting group. Distinct aggregate morphologies, which are facilitated by the non-covalent metal-metal and π-π stacking interactions, have been observed before and after photo-irradiation.

Keywords: malachite green; alkynylplatinum bis; photoactivable malachite; malachite; based alkynylplatinum; green based

Journal Title: Chemical communications
Year Published: 2024

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