Mn-mediated reductive cross-coupling of organic bromides with 2-bromo-1,3,2-diazaphospholene was developed for efficient construction of C-P bonds under mild conditions. Mechanistic studies suggested that bromides are activated by in situ formed… Click to show full abstract
Mn-mediated reductive cross-coupling of organic bromides with 2-bromo-1,3,2-diazaphospholene was developed for efficient construction of C-P bonds under mild conditions. Mechanistic studies suggested that bromides are activated by in situ formed bis-diazaphospholene via hybrid radical and polar mechanisms.
Keywords:
alkyl bromides;
aryl alkyl;
via mediated;
phosphination aryl;
mediated reductive;
bromides via
Journal Title: Chemical communications
Year Published: 2024
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Journal Title: Chemical communications
Year Published: 2024
Link to full text (if available)
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recommendations!