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A highly conductive and antioxidative MoO2-doped Li argyrodite electrolyte for all-solid-state Li batteries.

A MoO2-doped Li5.5PS4.5Cl1.5 solid electrolyte with ionic conductivity of 12 mS cm-1 and an electrochemical window of 4.3 V vs. Li/Li+ was prepared, which enables a LiNi0.8Co0.1Mn0.1O2-based full cell to… Click to show full abstract

A MoO2-doped Li5.5PS4.5Cl1.5 solid electrolyte with ionic conductivity of 12 mS cm-1 and an electrochemical window of 4.3 V vs. Li/Li+ was prepared, which enables a LiNi0.8Co0.1Mn0.1O2-based full cell to deliver a specific capacity of 194 mA h g-1 at 0.1C and retain 80% capacity after 3500 cycles at 1C.

Keywords: highly conductive; moo2; moo2 doped; electrolyte; conductive antioxidative; antioxidative moo2

Journal Title: Chemical communications
Year Published: 2024

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