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Topological and magnetic regulation in three cobalt(II) coordination polymers constructed by mixed bipyrimidine-tetracarboxylate strategy

Coordination compounds with slow magnetic relaxation are of great interest due to their magnetic bistability. Herein, three cobalt(II) coordination polymer, formulated as {[Co2(btca)(bpym)]·4H2O}n (1) and {[Co2(btca)(bpym)]·2DMF·2H2O}n (2), {[Co2(H2btca)2(bpym)]}n (3) (H4btca... Click to show full abstract

Coordination compounds with slow magnetic relaxation are of great interest due to their magnetic bistability. Herein, three cobalt(II) coordination polymer, formulated as {[Co2(btca)(bpym)]·4H2O}n (1) and {[Co2(btca)(bpym)]·2DMF·2H2O}n (2), {[Co2(H2btca)2(bpym)]}n (3) (H4btca...

Keywords: cobalt coordination; magnetic regulation; topological magnetic; three cobalt; coordination

Journal Title: CrystEngComm
Year Published: 2024

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