"Effect of nuclearity and reduction state of the central ligand on magnetic properties of hexaazatrinaphthylene-based cobalt(II) and iron(II) complexes: From extremely weak to record-breaking antiferromagnetic exchange interaction."

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Effect of nuclearity and reduction state of the central ligand on magnetic properties of hexaazatrinaphthylene-based cobalt(II) and iron(II) complexes: From extremely weak to record-breaking antiferromagnetic exchange interaction.

A series of hexaazatrinaphthylene (HATNA) and hexaazatrianthracene (HATA) complexes with high-spin cobalt(II) (S = 3/2) and iron(II) (S = 2) were synthesized. These compounds vary in charge of the central... Click to show full abstract

Keywords: cobalt; reduction state; cobalt iron; effect nuclearity; nuclearity reduction

Journal Title: Inorganic Chemistry Frontiers
Year Published: 2024

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