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Breaking the Symmetry of Sulfur Defect State via Atomic Substitution for Enhanced CO2 Photoreduction

Conventional sulfur vacancy, characterized by a symmetric coordination of metal cations (M1-SV-M1), typically serves as a catalytic site for CO2 chemisorption. However, the symmetric SV site, with a uniform charge... Click to show full abstract

Conventional sulfur vacancy, characterized by a symmetric coordination of metal cations (M1-SV-M1), typically serves as a catalytic site for CO2 chemisorption. However, the symmetric SV site, with a uniform charge...

Keywords: symmetry sulfur; breaking symmetry; sulfur; defect state; sulfur defect; state via

Journal Title: Journal of Materials Chemistry A
Year Published: 2024

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