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Enhancing acid–gas separations using free volume manipulation for microporous poly(arylene ether)s

H2S/CH4 and CO2/CH4 separations show opposing trends, making simultaneous improvement challenging. This is addressed by increasing free volume to enhance competitive sorption effects and boosting diffusion selectivity through in situ… Click to show full abstract

H2S/CH4 and CO2/CH4 separations show opposing trends, making simultaneous improvement challenging. This is addressed by increasing free volume to enhance competitive sorption effects and boosting diffusion selectivity through in situ crosslinking.

Keywords: gas separations; acid gas; free volume; separations using; enhancing acid; volume

Journal Title: Journal of Materials Chemistry A
Year Published: 2025

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