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New insights into cyclopropanation: application in the synthesis of a novel high-heating-value hydrocarbon fuel derived from furfural.

Cyclopropanation is crucial in synthesizing high-heating-value fuels. In situ experiments and computational studies provide new insights into the four-step cyclopropanation, where the high activity of Al carbenoid is attributed to… Click to show full abstract

Cyclopropanation is crucial in synthesizing high-heating-value fuels. In situ experiments and computational studies provide new insights into the four-step cyclopropanation, where the high activity of Al carbenoid is attributed to the electron shift from olefin to Al carbenoid and high proximity of Al carbenoid with olefin.

Keywords: new insights; cyclopropanation; heating value; insights cyclopropanation; high heating

Journal Title: Chemical communications
Year Published: 2025

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