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Coordination-assembly of a redox-active Pd6L3 cage for aerobic C(sp3)-H bond photooxidation of aromatic cyclic ethers.

A redox-active Pd6L3 cage with a large lantern-shaped cavity has been synthesized and characterised by NMR, ESI-TOF-MS and X-ray diffraction analysis, which shows exceptional catalytic activity in the selective aerobic… Click to show full abstract

A redox-active Pd6L3 cage with a large lantern-shaped cavity has been synthesized and characterised by NMR, ESI-TOF-MS and X-ray diffraction analysis, which shows exceptional catalytic activity in the selective aerobic C-H photooxidation of aromatic cyclic ethers under mild conditions.

Keywords: aromatic cyclic; active pd6l3; redox active; cyclic ethers; pd6l3 cage; photooxidation aromatic

Journal Title: Chemical communications
Year Published: 2025

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