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Reverse electron transfer in Ru/HfB2 drives selective hydrogenation via strong metal-support coupling.

Benzoic acid hydrogenation faces a persistent activity-selectivity trade-off. Ru/HfB2 overcomes this challenge via strong metal-support interactions that generate electron-rich Ruδ- sites, enabling >99% conversion and selectivity under optimized conditions. Click to show full abstract

Benzoic acid hydrogenation faces a persistent activity-selectivity trade-off. Ru/HfB2 overcomes this challenge via strong metal-support interactions that generate electron-rich Ruδ- sites, enabling >99% conversion and selectivity under optimized conditions.

Keywords: hydrogenation; via strong; hfb2; strong metal; metal support

Journal Title: Chemical communications
Year Published: 2025

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