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Cationic Substitution Engineering Induced New Quaternary Chalcogenide in A–MIIIA–MIVA–Q System Used for Optical Crystal

A new quaternary chalcogenide in A–MIIIA–MIVA–Q System, CsGaGe3S8, was synthesized via a high-temperature solid-state reaction. It crystallizes in the monoclinic system (space group P21/c) and features 2D ∞2 [(Ga/Ge)8S16]²⁻ layers... Click to show full abstract

A new quaternary chalcogenide in A–MIIIA–MIVA–Q System, CsGaGe3S8, was synthesized via a high-temperature solid-state reaction. It crystallizes in the monoclinic system (space group P21/c) and features 2D ∞2 [(Ga/Ge)8S16]²⁻ layers...

Keywords: system; new quaternary; miiia miva; chalcogenide miiia; miva system; quaternary chalcogenide

Journal Title: CrystEngComm
Year Published: 2025

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