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Impact of nuclear number on SHG and THG performances: A comparative study of chiral mono- and dinuclear TbIII complexes with identical organic ligands

The reactions between Tb(dbm)3(H2O) and chiral bis-bidentate N-donor, (+)-2,5-bis(4ʹ,5ʹ-pinene-2ʹ-pyridyl)pyrazine (S-L), in distinct molar ratios of 1:1 and 2:1, yielded two mono- and dinuclear chiral TbIII complexes, [Tb(dbm)3(S-L)]•2H2O (S-Tb-1) and [Tb2(dbm)6(S-L)]•4H2O... Click to show full abstract

The reactions between Tb(dbm)3(H2O) and chiral bis-bidentate N-donor, (+)-2,5-bis(4ʹ,5ʹ-pinene-2ʹ-pyridyl)pyrazine (S-L), in distinct molar ratios of 1:1 and 2:1, yielded two mono- and dinuclear chiral TbIII complexes, [Tb(dbm)3(S-L)]•2H2O (S-Tb-1) and [Tb2(dbm)6(S-L)]•4H2O...

Keywords: mono dinuclear; impact nuclear; tbiii complexes; nuclear number; number shg

Journal Title: CrystEngComm
Year Published: 2025

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