"Metal-free catalytic de novo construction of multi-functionalized trifluoromethylarenes through [3 + 3] benzannulation at low catalyst loadings"

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A low catalyst loading and transition metal-free benzannulation of β,γ-alkynyl-α-keto esters and CF3-alkenes has been developed through Michael-triggered [3 + 3] annulation. Click to show full abstract

A low catalyst loading and transition metal-free benzannulation of β,γ-alkynyl-α-keto esters and CF3-alkenes has been developed through Michael-triggered [3 + 3] annulation.

Keywords: benzannulation; metal free; free catalytic; catalytic novo; low catalyst

Journal Title: Organic Chemistry Frontiers
Year Published: 2025

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